Emission characterization and δ(13)C values of parent PAHs and nitro-PAHs in size-segregated particulate matters from coal-fired power plants

Ruwei Wang; Balal Yousaf; Ruoyu Sun; Hong Zhang; Jiamei Zhang; Guijian Liu

doi:10.1016/j.jhazmat.2016.07.030

Emission characterization and δ(13)C values of parent PAHs and nitro-PAHs in size-segregated particulate matters from coal-fired power plants

J Hazard Mater. 2016 Nov 15:318:487-496. doi: 10.1016/j.jhazmat.2016.07.030. Epub 2016 Jul 11.

Authors

Ruwei Wang¹, Balal Yousaf², Ruoyu Sun², Hong Zhang³, Jiamei Zhang², Guijian Liu⁴

Affiliations

¹ CAS Key Laboratory of Crust-Mantle Materials and the Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, The Chinese Academy of Sciences, Xi'an 710075 Shaanxi, China.
² CAS Key Laboratory of Crust-Mantle Materials and the Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China.
³ Anhui Department of Environmental Protection, Anhui Academy of Environmental Science, Hefei 230071, China.
⁴ CAS Key Laboratory of Crust-Mantle Materials and the Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, The Chinese Academy of Sciences, Xi'an 710075 Shaanxi, China. Electronic address: lgj@ustc.edu.cn.

PMID: 27450341
DOI: 10.1016/j.jhazmat.2016.07.030

Abstract

The objective of this study was to characterize parent polycyclic aromatic hydrocarbons (pPAHs) and their nitrated derivatives (NPAHs) in coarse (PM2.5-10), intermediate (PM1-2.5) and fine (PM1) particulate matters emitted from coal-fired power plants (CFPPs) in Huainan, China. The diagnostic ratios and the stable carbon isotopic approaches to characterize individual PAHs were applied in order to develop robust tools for tracing the origins of PAHs in different size-segregated particular matters (PMs) emitted CFPP coal combustion. The concentrations of PAH compounds in flue gas emissions varied greatly, depending on boiler types, operation and air pollution control device (APCD) conditions. Both pPAHs and NPAHs were strongly enriched in PM1-2.5 and PM1. In contrary to low molecular weight (LMW) PAHs, high molecular weight (HMW) PAHs were more enriched in finer PMs. The PAH diagnostic ratios in size-segregated PMs are small at most cases, highlighting their potential application in tracing CFPP emitted PAHs attached to different sizes of PMs. Yet, substantial uncertainty still exists to directly apply PAH diagnostic ratios as emission tracers. Although the stable carbon isotopic composition of PAH molecular was useful in differentiating coal combustion emissions from other sources such as biomass combustion and vehicular exhausts, it was not feasible to differentiate isotopic fractionation processes such as low-temperature carbonization, high-temperature carbonization, gasification and combustion.

Keywords: Coal-fired power plant (CFPP); PAHs; Size-segregated PMs; Source assessment; δ(13)C values.