A closer look on the coordination of soft nitrogen-donor ligands to Cm(iii): SO3-Ph-BTBP

M Trumm; C Wagner; B Schimmelpfennig; A Geist; P J Panak

doi:10.1039/c6dt02052f

A closer look on the coordination of soft nitrogen-donor ligands to Cm(iii): SO3-Ph-BTBP

Dalton Trans. 2016 Aug 2;45(31):12308-11. doi: 10.1039/c6dt02052f.

Authors

M Trumm¹, C Wagner², B Schimmelpfennig¹, A Geist¹, P J Panak²

Affiliations

¹ Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie, D-76131 Karlsruhe, Germany. Michael.Trumm@kit.edu.
² Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie, D-76131 Karlsruhe, Germany. Michael.Trumm@kit.edu and Ruprecht Karls Universität Heidelberg, Physikalisch-Chemisches Institut, Im Neuenheimer Feld 253, D-69120 Heidelberg, Germany. Christoph.Wagner@kit.edu.

PMID: 27441724
DOI: 10.1039/c6dt02052f

Abstract

We present a combined theoretical and experimental study on the recently developed hydrophilic SO3-Ph-BTBP ligand. Vibronic side band spectroscopy and time-resolved laser fluorescence spectroscopy (TRLFS) were employed to prove the theoretical prediction of the ligand's coordination mode.