Glass transition and stable glass formation of tetrachloromethane

Y Z Chua; M Tylinski; S Tatsumi; M D Ediger; C Schick

doi:10.1063/1.4954665

Glass transition and stable glass formation of tetrachloromethane

J Chem Phys. 2016 Jun 28;144(24):244503. doi: 10.1063/1.4954665.

Authors

Y Z Chua¹, M Tylinski², S Tatsumi³, M D Ediger², C Schick¹

Affiliations

¹ Institute of Physics, University of Rostock, Albert-Einstein-Str. 23-24, 18059 Rostock, Germany.
² Department of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, USA.
³ Department of Macromolecular Science and Engineering, Kyoto Institute of Technology, Kyoto 606-8585, Japan.

PMID: 27369523
DOI: 10.1063/1.4954665

Abstract

Physical vapor deposition (PVD) has been used to prepare organic glasses with very high kinetic stability and it has been suggested that molecular anisotropy is a prerequisite for stable glass formation. Here we use PVD to prepare glasses of tetrachloromethane, a simple organic molecule with a nearly isotropic molecular structure. In situ AC nanocalorimetry was used to characterize the vapor-deposited glasses. Glasses of high kinetic stability were produced by deposition near 0.8 Tg. The isothermal transformation of the vapor-deposited glasses into the supercooled liquid state gave further evidence that tetrachloromethane forms glasses with high kinetic stability, with the transformation time exceeding the structural relaxation time of the supercooled liquid by a factor of 10(3). The glass transition temperature of liquid-cooled tetrachloromethane is determined as Tg ≈ 78 K, which is different from previously reported values. The frequency dependence of the glass transition was also determined and the fragility was estimated as m ≈ 118. The successful formation of PVD glasses of tetrachloromethane which have high kinetic stability argues that molecular asymmetry is not a prerequisite for stable glass formation.