Discoloration of PMMA, composite, and PEEK

Clin Oral Investig. 2017 May;21(4):1191-1200. doi: 10.1007/s00784-016-1892-2. Epub 2016 Jun 25.

Abstract

Introduction: To assess the discoloration and stain removal potential of different cleaning methods relevant to individual/professional prophylaxis and laboratory cleaning on polyetheretherketone (PEEK), poly(methyl methacrylate) (PMMA)-based, and composite (COMP) materials after storage in different media for 7 days.

Methods: One thousand three hundred twenty specimens of PEEK, PMMA, and COMP (N = 440 of each group) were prepared and stored in four different media for 7 days to cause stain. Samples were divided into three cleaning groups (n = 10): (i) individual prophylaxis, (ii) laboratory protocols, and (iii) professional prophylaxis. Color was determined by a portable spectrophotometer and calculated between different time points (∆E). The data was statistically evaluated using univariate analyses, Kruskal-Wallis H and Mann-Whitney U tests (p < 0.05).

Results: The significantly (p < 0.001) lowest discoloration was found when specimens were stored in distilled water and chlorhexidine (CHX), followed by red wine. Curry solution caused the highest discoloration. PEEK showed the significantly (p < 0.001) lowest color changes, while COMP showed the highest changes. Ultrasonic bath and Air Flow Plus (AFP) were the significantly (p < 0.001) most effective methods to remove staining. The least cleaning effect was found using a soft toothbrush (ST), a medium-hard toothbrush (MT), and SunSparkle (SS) cleaning system.

Conclusions: PEEK seems more stable against discolorations than other denture resin materials. Regarding the cleaning potential, individual prophylaxis can be conducted with toothbrushes. For professional prophylaxis, air-abrasion devices using gentle powders are effective. Laboratory protocols should include gentle cleaning methods like ultrasonic bath.

Clinical relevance: Clinicians and dental technicians should inform their patients about the discoloration potential of certain foods/beverages and recommend the most efficient cleaning, but preventive methods.

Keywords: Cleaning; Discoloration; Polyetheretherketone; Surface free energy; Surface roughness.

MeSH terms

  • Benzophenones
  • Composite Resins / chemistry*
  • Dental Materials / chemistry*
  • Ketones / chemistry*
  • Materials Testing
  • Polyethylene Glycols / chemistry*
  • Polymers
  • Polymethyl Methacrylate / chemistry*
  • Prosthesis Coloring
  • Spectrophotometry
  • Surface Properties
  • Tooth Discoloration*
  • Toothbrushing

Substances

  • Benzophenones
  • Composite Resins
  • Dental Materials
  • Ketones
  • Polymers
  • polyetheretherketone
  • Polyethylene Glycols
  • Polymethyl Methacrylate