Microwave Heating of Functionalized Graphene Nanoribbons in Thermoset Polymers for Wellbore Reinforcement

ACS Appl Mater Interfaces. 2016 May 25;8(20):12985-91. doi: 10.1021/acsami.6b01756. Epub 2016 May 11.

Abstract

Here, we introduce a systematic strategy to prepare composite materials for wellbore reinforcement using graphene nanoribbons (GNRs) in a thermoset polymer irradiated by microwaves. We show that microwave absorption by GNRs functionalized with poly(propylene oxide) (PPO-GNRs) cured the composite by reaching 200 °C under 30 W of microwave power. Nanoscale PPO-GNRs diffuse deep inside porous sandstone and dramatically enhance the mechanics of the entire structure via effective reinforcement. The bulk and the local mechanical properties measured by compression and nanoindentation mechanical tests, respectively, reveal that microwave heating of PPO-GNRs and direct polymeric curing are major reasons for this significant reinforcement effect.

Keywords: graphene nanoribbon; mechanical reinforcement,; microwave; microwave induced heating; polymer composite.

Publication types

  • Research Support, Non-U.S. Gov't