Two novel bi-functional hybrid materials constructed from POMs and a Schiff base with excellent third-order NLO and catalytic properties

Gonghao Hu; Hao Miao; Hua Mei; Shuai Zhou; Yan Xu

doi:10.1039/c6dt00138f

Two novel bi-functional hybrid materials constructed from POMs and a Schiff base with excellent third-order NLO and catalytic properties

Dalton Trans. 2016 May 10;45(19):7947-51. doi: 10.1039/c6dt00138f.

Authors

Gonghao Hu¹, Hao Miao¹, Hua Mei¹, Shuai Zhou¹, Yan Xu²

Affiliations

¹ College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, P.R. China. yanxu@njtech.edu.cn.
² College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, P.R. China. yanxu@njtech.edu.cn and Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P.R. China.

PMID: 27117492
DOI: 10.1039/c6dt00138f

Abstract

The first polyoxometalates modified by a porphyrin-resembling planar Schiff base have been successfully designed and synthesized under hydrothermal conditions. The third-order NLO responses indicated that they are excellent third-order NLO materials. Their catalytic performances are also investigated.

Publication types

Research Support, Non-U.S. Gov't