The influence of carboxymethylcellulose (CMC) on the reactivity of Fe NPs toward decabrominated diphenyl ether: The Ni doping, temperature, pH, and anion effects

Chih-Ping Tso; Yang-Hsin Shih

doi:10.1016/j.jhazmat.2016.03.082

The influence of carboxymethylcellulose (CMC) on the reactivity of Fe NPs toward decabrominated diphenyl ether: The Ni doping, temperature, pH, and anion effects

J Hazard Mater. 2017 Jan 15;322(Pt A):145-151. doi: 10.1016/j.jhazmat.2016.03.082. Epub 2016 Mar 29.

Authors

Chih-Ping Tso¹, Yang-Hsin Shih²

Affiliations

¹ Department of Agricultural Chemistry, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 106, Taiwan, ROC. Electronic address: d00623002@ntu.edu.tw.
² Department of Agricultural Chemistry, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 106, Taiwan, ROC.

PMID: 27083057
DOI: 10.1016/j.jhazmat.2016.03.082

Abstract

Polybrominated diphenyl ethers (PBDEs) are commonly used brominated flame retardants in many products. They have accumulated in the environment and become widely dispersed. In this study, carboxymethylcellulose (CMC) was applied to modify nanoscale zerovalent iron (NZVI) and bimetallic Ni/Fe nanoparticles (NPs) to prevent NP aggregation. In this study the removal kinetics of the decabrominated diphenyl ethers (DBDE) with CMC-stabilized Fe NPs were evaluated. CMC-stabilized Ni/Fe NPs with an average size of 86.7nm contained metallic Fe⁰ and reduced Ni. The colloidal stability decreased with a decrease in pH, which was further accompanied by a change in the removal rate of DBDE. Our results showed that anions do not change the removal rates of DBDE, with the exception of 10mM NO₃^-, which induced the formation of Fe (hydro)oxides on the Fe NP surface, which could further coagulate with DBDE. This study provides important information for our understanding of the influence of CMC coatings on the reactivity of Fe NPs. Because CMC coatings prevent the passivation of Fe in the presence of anions, CMC-coated Fe NPs show potential for the in-situ remediation of PBDEs in the environment.

Keywords: Anion; Carboxymethyl cellulose (CMC); Decabrominated diphenyl ethers (DBDE); Nanoscale zero-valent iron (NZVI); Stabilized Fe nanoparticles (NPs).