Crystal structure of Sr2CdPt2 containing linear platinum chains

Acta Crystallogr E Crystallogr Commun. 2016 Jan 9;72(Pt 2):144-6. doi: 10.1107/S2056989015024937. eCollection 2016 Feb 1.

Abstract

The ternary inter-metallic title phase, distrontium cadmium diplatinum, was prepared from stoichiometric amounts of the elements at 1123 K for one day. The crystal structure adopts the ortho-rhom-bic Ca2GaCu2 structure type in space group Immm. Its main features are characterized by linear (Pt-Pt⋯Pt-Pt) n chains that are aligned along [010] and condensed through cadmium atoms forming Cd-centred Pt2Cd2/2 rectangles to build up sheets parallel to (001). These sheets are connected to each other via alternating (001) sheets of strontium atoms along [001]. The strontium sheets consists of corrugated Sr4 units that are condensed to each other through edge-sharing parallel to [100].

Keywords: crystal structure; inter­metallic compound; linear platinum chains.