Crystal structure of (Z)-3-allyl-5-(4-methyl-benzyl-idene)-2-sulfanyl-idene-1,3-thia-zolidin-4-one

Rahhal El Ajlaoui; El Mostapha Rakib; Mohammed Chigr; Mohamed Saadi; Lahcen El Ammari

doi:10.1107/S2056989015020460

Crystal structure of (Z)-3-allyl-5-(4-methyl-benzyl-idene)-2-sulfanyl-idene-1,3-thia-zolidin-4-one

Acta Crystallogr E Crystallogr Commun. 2015 Nov 4;71(Pt 12):o906-7. doi: 10.1107/S2056989015020460. eCollection 2015 Dec 1.

Authors

Rahhal El Ajlaoui¹, El Mostapha Rakib¹, Mohammed Chigr¹, Mohamed Saadi², Lahcen El Ammari²

Affiliations

¹ Laboratoire de Chimie Organique et Analytique, Université Sultan Moulay Slimane, Faculté des Sciences et Techniques, Béni-Mellal, BP 523, Morocco.
² Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V, Avenue Ibn Battouta, BP 1014, Rabat, Morocco.

Abstract

In the title compound, C14H13NOS2, the atoms of the allyl group are disordered over two sets of sites, with an occupancy ratio of 0.559 (10):0.441 (10). The rhodanine ring makes a dihedral angle of 5.51 (12)° with the mean plane through the p-tolyl group. There are no specific inter-molecular inter-actions in the crystal packing.

Keywords: 1,3-thiazolidin-4-one; biological activity; crystal structure; rhodanine-based molecules.