Synthesis and spectroscopic behaviour of metal complexes of meso-alkylidenyl carbaporphyrinoids and their expanded analogues

Dalton Trans. 2016 Feb 21;45(7):3093-101. doi: 10.1039/c5dt04566e. Epub 2016 Jan 14.

Abstract

Treatment of meso-malonylidene-(m-benzi)porphyrin and meso-malonylidene-(m-benzi)pentaphyrin with Pd(ii), Au(iii), Ni(ii) and Ag(i) afforded the corresponding metal complexes. The synthesized metal complexes were characterized by spectroscopy including single crystal X-ray, NMR and mass spectrometry. Most metal complexes were stable in solution. The metal complexes showed strong absorption in the near IR region.

Publication types

  • Research Support, Non-U.S. Gov't