Construction of supramolecular polymer by enzyme-triggered covalent condensation of CB[8]-FGG-based supramonomer

Chem Commun (Camb). 2016 Feb 4;52(10):2083-6. doi: 10.1039/c5cc09103a.

Abstract

A rapid and effective enzymatic strategy for the fabrication of a supramolecular polymer is presented for the first time, in which a bifunctional ternary host-guest supramonomer is first prepared followed by subsequent enzymatic coupling of supramonomers.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Binding Sites
  • Bridged-Ring Compounds / chemistry*
  • Glycine / chemistry*
  • Horseradish Peroxidase / chemistry*
  • Horseradish Peroxidase / metabolism
  • Imidazoles / chemistry*
  • Macromolecular Substances / chemistry*
  • Models, Molecular
  • Oligopeptides / chemistry*
  • Phenylalanine / chemistry*
  • Polymers / chemistry*

Substances

  • Bridged-Ring Compounds
  • Imidazoles
  • Macromolecular Substances
  • Oligopeptides
  • Polymers
  • cucurbit(8)uril
  • Phenylalanine
  • Horseradish Peroxidase
  • Glycine