Approximate Analytic Expression for the Electrophoretic Mobility of Moderately Charged Cylindrical Colloidal Particles

Langmuir. 2015 Dec 29;31(51):13633-8. doi: 10.1021/acs.langmuir.5b02969. Epub 2015 Dec 16.

Abstract

An approximate analytic expression for the electrophoretic mobility of an infinitely long cylindrical colloidal particle in a symmetrical electrolyte solution in a transverse electric field is obtained. This mobility expression, which is correct to the order of the third power of the zeta potential ζ of the particle, considerably improves Henry's mobility formula correct to the order of the first power of ζ (Proc. R. Soc. London, Ser. A 1931, 133, 106). Comparison with the numerical calculations by Stigter (J. Phys. Chem. 1978, 82, 1417) shows that the obtained mobility formula is an excellent approximation for low-to-moderate zeta potential values at all values of κa (κ = Debye-Hückel parameter and a = cylinder radius).

MeSH terms

  • Colloids / chemistry*
  • Electrophoresis*
  • Models, Theoretical*
  • Particle Size
  • Surface Properties

Substances

  • Colloids