Crystal structure of dimethyl 9H-carbazole-2,7-di-carb-oxy-late

Acta Crystallogr E Crystallogr Commun. 2015 Sep 26;71(Pt 10):o784-5. doi: 10.1107/S2056989015017557. eCollection 2015 Oct 1.

Abstract

In the title compound, C16H13NO4, the carbazole ring system is almost planar with non-H atoms possessing a mean deviation from planarity of 0.037 Å. The two ester groups are orientated trans to one another and tilted slightly from the mean plane of the carbazole ring system, making dihedral angles of 8.12 (6) and 8.21 (5)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O hydrogen bonds forming inversion dimers. The dimers are linked by parallel slipped π-π inter-actions, forming slabs propagating along the b-axis direction [inter-centroid distance = 3.6042 (8) Å, inter-planar distance = 3.3437 (5) Å, slippage = 1.345 Å].

Keywords: carbazoles; crystal structure; hydrogen bonding; π–π inter­actions.