Abstract
A series of zirconium-based porous coordination polymers (PCPs) containing FI catalysts in the frameworks have been developed and studied as catalysts for ethylene polymerization. These PCPs exhibit good catalytic activities and long life times, producing polyethylenes with high molecular weights and bimodal molecular weight distribution in the form of particles.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Ethylenes / chemical synthesis*
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Ethylenes / chemistry
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Imines / chemistry*
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Molecular Structure
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Particle Size
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Phenols / chemistry*
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Polymerization
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Polymers / chemical synthesis*
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Polymers / chemistry
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Porosity
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Surface Properties
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Zirconium / chemistry*
Substances
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Ethylenes
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Imines
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Organometallic Compounds
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Phenols
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Polymers
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phenoxy radical
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ethylene
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Zirconium