The flower heads of Microliabum polymnioides afforded scopoletin, 5,4'-dihydroxy-3,6,7-trimethoxyflavone, 3,5,4'-trihydroxy-6,7-dimethoxyflavone and 3,5,7,4'-tetrahydroxy-6-methoxyflavone. The leaves contained hexadecanoic acid, phytol and docosane. This is the first report on the presence of 6-methoxyflavonoids in Microliabum genus.