Massive PCDD/F contamination at the Khimprom organochlorine plant in Ufa--a review and recommendations for future management

Environ Sci Pollut Res Int. 2015 Oct;22(19):14416-30. doi: 10.1007/s11356-015-5048-8. Epub 2015 Jul 24.

Abstract

The Khimprom plant in Ufa was one of the largest organochlorine production facilities in Russia. This paper summarises the residual pollution of the site with polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and highlights the current and future challenges in relation to remediation of the site. Preliminary assessment of the pollution shows large-scale PCDD/F contamination at the site from half a century production of organochlorine pesticides and solvents. This contamination is affecting the city, and 2500 residents live within 3 km with a further 350,000 living within 7 km of the factory. The current PCDD/F pollution of the site and the continuing releases highlight the urgent need for further investigations, for the site to be secured and for the contamination to be remediated. The production history of the plant means that also other unintentionally POPs, mercury and chlorinated solvents need to be considered. The current regulatory framework for PCDD/F-contaminated soil and for defining hazardous waste in the Russian Federation is not appropriate for the management of PCDD/F-contaminated sites. It is therefore suggested that a science-based regulatory framework should be developed. The Russian Federation recently ratified the Stockholm Convention providing a foundation for the development of appropriate regulations and for further assessment, securing and remediation of the site. The impacts of pollution from the Khimprom plant demonstrate that the assessment and management of the organochlorine production sites should be a priority in the implementation of the Stockholm Convention by the Russian Federation and other countries.

Keywords: 2,4,5-T; Chloralkali; Contaminated site; Dioxin; HCBD; Organochlorine production.

Publication types

  • Research Support, Non-U.S. Gov't
  • Review

MeSH terms

  • Bashkiria
  • Benzofurans / analysis*
  • Chemical Industry* / trends
  • Cities
  • Dibenzofurans, Polychlorinated
  • Environmental Monitoring / methods*
  • Environmental Pollutants / analysis*
  • Hazardous Waste / analysis*
  • Polychlorinated Dibenzodioxins / analogs & derivatives*
  • Polychlorinated Dibenzodioxins / analysis

Substances

  • Benzofurans
  • Dibenzofurans, Polychlorinated
  • Environmental Pollutants
  • Hazardous Waste
  • Polychlorinated Dibenzodioxins