Optimization and modeling of reduction of wastewater sludge water content and turbidity removal using magnetic iron oxide nanoparticles (MION)

J Environ Sci Health A Tox Hazard Subst Environ Eng. 2015;50(13):1307-15. doi: 10.1080/10934529.2015.1030275. Epub 2015 Jul 16.

Abstract

Economic and rapid reduction of sludge water content in sewage wastewater is difficult and requires special advanced treatment technologies. This study focused on optimizing and modeling decreased sludge water content (Y1) and removing turbidity (Y2) with magnetic iron oxide nanoparticles (Fe3O4, MION) using a central composite design (CCD) and response surface methodology (RSM). CCD and RSM were applied to evaluate and optimize the interactive effects of mixing time (X1) and MION concentration (X2) on chemical flocculent performance. The results show that the optimum conditions were 14.1 min and 22.1 mg L(-1) for response Y1 and 16.8 min and 8.85 mg L(-1) for response Y2, respectively. The two responses were obtained experimentally under this optimal scheme and fit the model predictions well (R(2) = 97.2% for Y1 and R(2) = 96.9% for Y2). A 90.8% decrease in sludge water content and turbidity removal of 29.4% were demonstrated. These results confirm that the statistical models were reliable, and that the magnetic flocculation conditions for decreasing sludge water content and removing turbidity from sewage wastewater were appropriate. The results reveal that MION are efficient for rapid separation and are a suitable alterative to sediment sludge during the wastewater treatment process.

Keywords: Magnetic iron oxide nanoparticles (MION); RSM; mixing time; sludge water content; turbidity.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Ferric Compounds / chemistry*
  • Flocculation
  • Magnetics
  • Metal Nanoparticles / chemistry*
  • Models, Chemical
  • Models, Theoretical
  • Reproducibility of Results
  • Sewage / chemistry*
  • Water / chemistry
  • Water Purification / methods

Substances

  • Ferric Compounds
  • Sewage
  • Water
  • ferric oxide