Mechanical switching of magnetic interaction by tweezers-type complex

Chem Commun (Camb). 2015 Aug 21;51(65):12916-9. doi: 10.1039/c5cc04980f.

Abstract

A control of the interaction between two spin centers was achieved by using a mechanical motion in a terpy(Cu-salphen)2 complex. Upon coordination a conformation change and switching from a paramagnetic to an antiferromagnetically coupled system was observed by EPR and SQUID measurements.