Hybrid materials of Ni NP@MOF prepared by a simple synthetic method

Megumi Mukoyoshi; Hirokazu Kobayashi; Kohei Kusada; Mikihiro Hayashi; Teppei Yamada; Mitsuhiko Maesato; Jared M Taylor; Yoshiki Kubota; Kenichi Kato; Masaki Takata; Tomokazu Yamamoto; Syo Matsumura; Hiroshi Kitagawa

doi:10.1039/c5cc04663g

Hybrid materials of Ni NP@MOF prepared by a simple synthetic method

Chem Commun (Camb). 2015 Aug 11;51(62):12463-6. doi: 10.1039/c5cc04663g.

Authors

Megumi Mukoyoshi¹, Hirokazu Kobayashi, Kohei Kusada, Mikihiro Hayashi, Teppei Yamada, Mitsuhiko Maesato, Jared M Taylor, Yoshiki Kubota, Kenichi Kato, Masaki Takata, Tomokazu Yamamoto, Syo Matsumura, Hiroshi Kitagawa

Affiliation

¹ Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan. hkobayashi@kuchem.kyoto-u.ac.jp kitagawa@kuchem.kyoto-u.ac.jp.

PMID: 26144844
DOI: 10.1039/c5cc04663g

Abstract

We demonstrate a novel, simple synthetic method for metal (Ni) NPs in a MOF using the partial thermal decomposition of nickel(II) 2,5-dihydroxyterephthalate (Ni-MOF-74). The Ni NPs inside the Ni-MOF-74 are several nanometers in size, and the size can be precisely controlled by the heating conditions.