The introduction of multiple carbon rings is one of the common ways for graphene modification. Starting from warped C80H30 nanographene, which consists of a number of six- and seven-membered carbon rings (C6 and C7) centering at a five-membered carbon ring (C5), we explored the structure and property variations of its derivatives in which their C7 rings were gradually replaced with C6 rings. With reducing number of C7 rings, their curved boundary with the C6 rings becomes flat until a bowl-like structure is formed when all the C7 rings disappear. The optical absorption spectra vary accordingly. Both the α-bands and the maximum absorption bands in the visible region are related to the number and location of the C7 rings. Further analysis of the excited states of the C80H30 derivatives, as well as on the designed model systems, revealed that the C7 rings affect the electron excitations in two ways. In addition to their participation in electronic transitions, they control the composition of molecular orbitals that are involved in the excitations. The highest occupied molecular orbitals are mainly contributed by atoms on the C6 and C7 rings, while the lowest unoccupied molecular orbitals by atoms on the C5 and C6 rings. Our study sheds some light on how the multiple carbon rings affect the optical absorption of nanographenes and provides information for the preparation of nanographenes with tunable structural and optical properties.