Massive failure of TiNbN coating in surface engineered metal-on-metal hip arthroplasty: Retrieval analysis

J Biomed Mater Res B Appl Biomater. 2016 Jul;104(5):1043-9. doi: 10.1002/jbm.b.33421. Epub 2015 May 14.

Abstract

This article presents examination of a failed total hip replacement with surface engineered metal-on-metal (MoM) articulation. The implant was coated with a thin TiNbN film (Physical Vapor Deposition), and at retrieval 53 months after implantation the coating was abraded on weight-bearing part of the head and acetabular component. Scanning electron microscopy of bearing surfaces demonstrated multifocal crack formation, delamination of small film fragments, and formation of aggregates containing nanometer sized wear debris. We also observed coating damage in third body mechanism. Complex failure mechanism of TiNbN coating demonstrated in this study suggests insufficient bonding strength between the coating and substrate alloy and raise concerns regarding the use of such coatings in total hip arthroplasty with MoM bearing. © 2015 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 104B: 1043-1049, 2016.

Keywords: arthroplasty; bearing surfaces; coating(s); failure analysis; wear.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alloys / chemistry*
  • Arthroplasty, Replacement, Hip*
  • Coated Materials, Biocompatible / chemistry*
  • Female
  • Hip Prosthesis*
  • Humans
  • Middle Aged
  • Niobium / chemistry
  • Prosthesis Failure*
  • Titanium / chemistry

Substances

  • Alloys
  • Coated Materials, Biocompatible
  • Niobium
  • Titanium