Facile synthesis of pure 1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxy bisanhydride and bisimide

Rajeev K Dubey; Nick Westerveld; Ferdinand C Grozema; Ernst J R Sudhölter; Wolter F Jager

doi:10.1021/acs.orglett.5b00562

Facile synthesis of pure 1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxy bisanhydride and bisimide

Org Lett. 2015 Apr 17;17(8):1882-5. doi: 10.1021/acs.orglett.5b00562. Epub 2015 Mar 26.

Authors

Rajeev K Dubey, Nick Westerveld, Ferdinand C Grozema, Ernst J R Sudhölter, Wolter F Jager¹

Affiliation

¹ §BioSolar Cells, P.O. Box 98, 6700 AB Wageningen, The Netherlands.

PMID: 25811248
DOI: 10.1021/acs.orglett.5b00562

Abstract

A robust and scalable procedure to obtain pure 1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxy bisanhydride, a highly valuable synthon, has been developed via synthesis of a novel intermediate compound 1,6,7,12-perylene-3,4,9,10-tetracarboxy tetrabutylester.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Imides / chemical synthesis*
Imides / chemistry
Molecular Structure
Perylene / analogs & derivatives*
Perylene / chemical synthesis
Perylene / chemistry

Substances

Imides
Perylene