Versatile synthesis of phospholides from open-chain precursors. Application to annelated pyrrole- and silole-phosphole rings

Youzhi Xu; Zhihua Wang; Zhenjie Gan; Qiuzhen Xi; Zheng Duan; François Mathey

doi:10.1021/acs.orglett.5b00598

Versatile synthesis of phospholides from open-chain precursors. Application to annelated pyrrole- and silole-phosphole rings

Org Lett. 2015 Apr 3;17(7):1732-4. doi: 10.1021/acs.orglett.5b00598. Epub 2015 Mar 23.

Authors

Youzhi Xu¹, Zhihua Wang¹, Zhenjie Gan¹, Qiuzhen Xi¹, Zheng Duan¹, François Mathey¹

Affiliation

¹ †College of Chemistry and Molecular Engineering, International Phosphorus Laboratory, Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, P. R. China.

PMID: 25797287
DOI: 10.1021/acs.orglett.5b00598

Abstract

Phospholides are easily obtained by treatment of the open-chain acetylenic phosphines shown by an excess of lithium at room temperature in THF (12 examples).