Superconductivity and the periodic table: from elements to materials

Philos Trans A Math Phys Eng Sci. 2015 Mar 13;373(2037):20140192. doi: 10.1098/rsta.2014.0192.

Abstract

Based on the normal-state electronic band structure, the necessary condition for a metal to become a superconductor is the simultaneous occurrence of flat and steep bands at the Fermi level. The sufficient condition at least for conventional superconductors is a strong enough coupling of the flat band states to the lattice, e.g. via phonons. Selected elements (Te) and compounds of the rare earth metals (RE(2)C(3), REC(2), RE(2)X(2)C(2) with X=halogen) and MgB(2) serve as examples to illustrate the idea.

Keywords: carbide halides; carbides; magnesium diboride; rare earths; tellurium.