Ellipsoid-shaped superparamagnetic nanoclusters through emulsion electrospinning

Chem Commun (Camb). 2015 Mar 4;51(18):3758-61. doi: 10.1039/c4cc10076j.

Abstract

Ellipsoid-shaped nanoclusters composed of single superparamagnetic nanoparticles can be generated by emulsion electrospinning. Stretching and subsequent solvent evaporation of iron oxide loaded emulsion droplets during the emulsion electrospinning process enables the creation of such structures embedded in polymer nanofibers. Dissolution of the polymer fibers yields an aqueous dispersion of the inorganic clusters which are the first example of ellipsoid-shaped superparamagnetic nanoclusters with a high saturation magnetization (∼47 emu g(-1)).

MeSH terms

  • Emulsions
  • Ferric Compounds / chemistry*
  • Magnetic Phenomena
  • Microscopy, Electron, Scanning
  • Microscopy, Electron, Scanning Transmission
  • Nanostructures / chemistry*
  • Nanostructures / ultrastructure
  • Octanes / chemistry
  • Polyvinyl Alcohol / chemistry*

Substances

  • Emulsions
  • Ferric Compounds
  • Octanes
  • ferric oxide
  • Polyvinyl Alcohol
  • octane