TDAE strategy in the benzoxazolone series: synthesis and reactivity of a new benzoxazolinonic anion

Molecules. 2015 Jan 14;20(1):1262-76. doi: 10.3390/molecules20011262.

Abstract

We describe an original pathway to produce new 5-substituted 3-methyl-6-nitro-benzoxazolones by the reaction of aromatic carbonyl and α-carbonyl ester derivatives with a benzoxazolinonic anion formed exclusively via the TDAE strategy.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Anions / chemistry
  • Benzoxazoles / chemical synthesis*
  • Benzoxazoles / chemistry
  • Carbon-13 Magnetic Resonance Spectroscopy
  • Dimethylamines / chemistry*
  • Ethylenes / chemistry*
  • Proton Magnetic Resonance Spectroscopy
  • Spectrometry, Mass, Electrospray Ionization

Substances

  • Anions
  • Benzoxazoles
  • Dimethylamines
  • Ethylenes
  • tetrakis(dimethylamino)ethylene