Quantum phase transitions occur when the ground state of a Hamiltonian undergoes qualitative changes with a control parameter changing. In this paper we consider a particular system--an Isng-type spin ring with competing many-body interactions. Depending on the relative strength interactions, the ground state of the system is either a product state or entangled state. We implement the system in a cavity-assisted neutral atomic simulator and study the non-locality and entanglement of the simulated ground state of an Ising-type three-spin ring with the control parameter changing. The simplicity of the setup and its robustness to noise give it a great practicality within the framework of current experimental technology.