Application of montmorillonite-Cu(II)ethylenediamine catalyst for the decolorization of Chromotrope 2R with H₂O₂ in aqueous solution

Abstract

The kinetics of decolorization of Chromotrope 2R (C2R) was studied spectrophotometrically using the montmorilloniteK10-Cu(II)ethylenediamine composite (MMTK10-Cu(en)2) as catalyst and H2O2 as oxidant in aqueous solution. The catalyst was prepared and characterized by SEM, FTIR, XRD and TGA techniques. The dependence of reaction rate on H2O2 concentration was examined under UV irradiation in the presence and absence of the catalyst, and in the presence of the catalyst without the UV irradiation. In all these reaction systems, the rate increased up to a maximum value and then decreased. The rate increased with increasing the concentration of the dye reaching a maximum. Also, the rate of decolorization reaction showed a significant increase with increasing the amount of the catalyst and temperature. The addition of NaCl to the reaction medium has accelerated the rate effectively. A similar catalyst, MMTKSF-Cu(en)2, has also been employed and was found to be less efficient compared with MMTK10-Cu(en)2.

Keywords: Chromotrope 2R; Copper(II)-ethylenediamine complex; Decolorization; H(2)O(2); Montmorillonite; Textile dyes.