Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione

Acta Crystallogr Sect E Struct Rep Online. 2014 Nov 29;70(Pt 12):o1297. doi: 10.1107/S1600536814025768. eCollection 2014 Dec 1.

Abstract

In the title compound, C9H15NO2, the piperidine ring exhibits a chair conformation. The butane-dione subunit exhibits a conformation with the ketone C atom in an eclipsed position with respect to the amide carbonyl group. In the crystal, a two-dimensional layered arrangement is formed by hydrogen bonds of the C-H⋯O type between the methyl group and the exocyclic methyl-ene unit as donor sites and the amide carbonyl O atom as the acceptor of a bifurcated hydrogen bond. These layers are oriented parallel to the ab plane.

Keywords: 1-(piperidin-1-yl)butane-1,3-dione; crystal structure; weak hydrogen bonding.