Latest approaches on green chemistry preconcentration methods for trace metal determination in seawater--a review

Abstract

Evaluation of trace metal levels in seawater samples is undertaken regularly by research groups all over the world, leading to a growing demand for techniques involving fewer toxic reagents, less time-consuming protocols and lower limits of detection. This review focuses on providing a brief but concise description of the latest methodologies developed to this end, outlining the advantages and disadvantages of the various protocols, chelating and dispersive agents and instruments used. Conclusions are drawn on the basis of the articles reviewed, highlighting improvements introduced in order to enhance the performance of the protocols.

Keywords: Liquid–liquid microextraction techniques; Preconcentration techniques; Seawater; Trace metals.