Seamless stitching of graphene domains on polished copper (111) foil

Adv Mater. 2015 Feb 25;27(8):1376-82. doi: 10.1002/adma.201404541. Epub 2014 Dec 18.

Abstract

Seamless stitching of graphene domains on polished copper (111) is proved clearly not only at atomic scale by scanning tunnelling microscopy (STM) and transmission electron micoscopy (TEM), but also at the macroscale by optical microscopy after UV-treatment. Using this concept of seamless stitching, synthesis of 6 cm × 3 cm monocrystalline graphene without grain boundaries on polished copper (111) foil is possible, which is only limited by the chamber size.

Keywords: UV-treatment; chemical vapor deposition (CVD); grain boundary; graphene growth; liquid crystals.