1 Department Química Física i Inorgànica, University Rovira i Virgili, C/Marcel·lí Domingo s/n, Tarragona, Spain. mariaelena.fernandez@urv.cat j.carbo@urv.cat.
Experimental and theoretical rationalization on regioselective mixed diboration of alkenes, with the unsymmetrical diboron reagent Bpin-Bdan, providing the protecting Bdan moiety in the internal position.