Catalytic dehydration of carbohydrates suspended in organic solvents promoted by AlCl3 /SiO2 coated with choline chloride

Abstract

We show that the coating of choline chloride on silica-supported AlCl3 allows the dehydration of carbohydrates to successfully proceed in low boiling point organic solvents. The concept is based on the in situ formation of a deep eutectic liquid phase on the catalyst surface, thus facilitating the interaction between the solid catalyst and insoluble carbohydrate.

Keywords: 5-hydroxymethylfurfural; biomass; carbohydrates; catalysis; choline chloride.