Potential-controlled rotaxane molecular shuttles based on electron-deficient macrocyclic complexes

Chem Commun (Camb). 2014 Nov 18;50(89):13718-21. doi: 10.1039/c4cc06718e.

Abstract

This communication reports a novel sandwich-like rotaxane shuttle, which exhibits a unique mode of potential-controlled behaviour. Two dynamic processes occur simultaneously - conformational "unfolding" of the DADA stack accompanies translocation of the ring over the rotaxane's axle.