Straightforward installation of carbon-halogen, carbon-oxygen and carbon-carbon bonds within metal-organic frameworks (MOF) via palladium-catalysed direct C-H functionalization

Tao Liu; Da-Qiang Li; Si-Yu Wang; Yong-Zhou Hu; Xiao-Wu Dong; Xin-Yuan Liu; Chi-Ming Che

doi:10.1039/c4cc05222f

Straightforward installation of carbon-halogen, carbon-oxygen and carbon-carbon bonds within metal-organic frameworks (MOF) via palladium-catalysed direct C-H functionalization

Chem Commun (Camb). 2014 Nov 11;50(87):13261-4. doi: 10.1039/c4cc05222f. Epub 2014 Sep 18.

Authors

Tao Liu¹, Da-Qiang Li, Si-Yu Wang, Yong-Zhou Hu, Xiao-Wu Dong, Xin-Yuan Liu, Chi-Ming Che

Affiliation

¹ ZJU-ENS Joint Laboratory of Medicinal Chemistry, College of Pharmaceutical Sciences, Zhejiang University, Hangzhou, 310058, P. R. China. dongxw@zju.edu.cn.

PMID: 25232794
DOI: 10.1039/c4cc05222f

Abstract

The straightforward C-H functionalization of UiO-67-dcppy materials was realized by a Pd-catalysed PSM. This novel protocol provides an efficient method for the synthesis of various functionalized MOFs, which have shown promising adsorbent ability in removing phenolic contaminates from water.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Adsorption
Carbon / chemistry*
Catalysis
Halogens / chemistry*
Molecular Structure
Organometallic Compounds / chemical synthesis
Organometallic Compounds / chemistry*
Oxygen / chemistry*
Palladium / chemistry*
Phenols / chemistry
Phenols / isolation & purification
Water Pollutants, Chemical / chemistry
Water Pollutants, Chemical / isolation & purification

Substances

Halogens
Organometallic Compounds
Phenols
Water Pollutants, Chemical
Palladium
Carbon
Oxygen