Abstract
Asymmetric synthesis of P-chiral phosphorothioic monofluoridic acid ammonium salts was achieved via axis-to-center chirality transfer reactions by using phosphorothioic acid O-esters with a binaphthyl group, and the absolute stereochemistry of the salts was determined by X-ray analyses and by comparison of their CD spectra.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Ammonium Compounds / chemical synthesis
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Ammonium Compounds / chemistry*
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Crystallography, X-Ray
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Fluorides / chemical synthesis
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Fluorides / chemistry*
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Halogenation
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Hydrolysis
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Models, Molecular
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Naphthalenes / chemistry
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Phosphoric Acids / chemical synthesis
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Phosphoric Acids / chemistry*
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Salts / chemistry*
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Stereoisomerism
Substances
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Ammonium Compounds
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Naphthalenes
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Phosphoric Acids
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Salts
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Fluorides