Electrical conduction behavior of organic light-emitting diodes using fluorinated self-assembled monolayer with molybdenum oxide-doped hole transporting layer

Luminescence. 2015 Jun;30(4):416-9. doi: 10.1002/bio.2753. Epub 2014 Aug 14.

Abstract

The electrical conductivity behavior of a fluorinated self-assembled monolayer (FSAM) of a molybdenum oxide (MoOx)-doped α-naphthyl diamine derivative (α-NPD) in organic light-emitting diodes (OLEDs) was investigated. The current density of the MoOx-doped α-NPD/FSAM device was proportional to its voltage owing to smooth carrier injection through the FSAM and the high carrier density of its bulk. The temperature-dependent characteristics of this device were investigated. The current density-voltage characteristics at different temperatures were almost the same owing to its very low activation energy. The activation energy of the device was estimated to be 1.056 × 10(-2) [eV] and was very low due to the inelastic electron tunneling of FSAM molecules.

Keywords: molybdenum oxide; organic light-emitting diodes; self-assembled monolayer; space charge limited current.

MeSH terms

  • Electric Conductivity
  • Equipment Design
  • Lighting / instrumentation*
  • Molybdenum / chemistry*
  • Oxides / chemistry
  • Temperature

Substances

  • Oxides
  • molybdenum dioxide
  • Molybdenum