Improvement of polyvinyl alcohol properties by adding nanocrystalline cellulose isolated from banana pseudostems

Carbohydr Polym. 2014 Nov 4:112:165-72. doi: 10.1016/j.carbpol.2014.05.090. Epub 2014 Jun 6.

Abstract

Cellulose nanocrystals (CNCs) isolated from banana pseudostems fibers (BPF) of the Pacovan variety were used as fillers in a polyvinyl alcohol (PVOH) matrix to yield a nanocomposite. The fibers from the external fractions of the BPF were alkaline bleached and hydrolyzed under acidic conditions (H2SO4 62% w/w, 70 min, 45 °C) to obtain CNCs with a length (L) of 135.0 ± 12.0 nm and a diameter (D) of 7.2 ± 1.9 nm to yield an aspect ratio (L/D) of 21.2. The CNCs were applied to PVOH films at different concentrations (0%, 1%, 3%, and 5% w/w, dry basis). With higher concentrations of CNCs, the water-vapor barrier of the films increased, while the optical properties changed very little. Increasing the concentration of the CNCs up to 3% significantly improved the mechanical properties of the nanocomposite.

Keywords: Agribusiness; Casting; Musa sp.; Nanocrystals; Nanotechnology; Packaging.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cellulose / chemistry*
  • Color
  • Microscopy, Electron, Transmission
  • Musa / chemistry*
  • Nanocomposites / chemistry
  • Nanoparticles / chemistry*
  • Polyvinyl Alcohol / chemistry*
  • Spectroscopy, Fourier Transform Infrared
  • Steam
  • Thermogravimetry

Substances

  • Steam
  • Polyvinyl Alcohol
  • Cellulose