A novel single-side azobenzene-grafted Anderson-type polyoxometalate for recognition-induced chiral migration

Chem Commun (Camb). 2014 Sep 25;50(74):10823-6. doi: 10.1039/c4cc04442h.

Abstract

A three-component supramolecular hybrid system based on host-guest recognition and electrostatic interaction has been developed for a consecutive chiral transfer from an alpha-cyclodextrin to cationic dyes via the bridge of a new azobenzene-grafted Anderson-type polyoxometalate cluster.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Azo Compounds / chemistry*
  • Cations / chemistry
  • Coloring Agents / chemistry
  • Methylene Blue / chemistry
  • Spectrophotometry, Ultraviolet
  • Static Electricity
  • Stereoisomerism
  • Tungsten Compounds / chemistry*
  • alpha-Cyclodextrins / chemistry

Substances

  • Azo Compounds
  • Cations
  • Coloring Agents
  • Tungsten Compounds
  • alpha-Cyclodextrins
  • polyoxometalate I
  • azobenzene
  • Methylene Blue
  • alpha-cyclodextrin