1-(2-Bromo-4-chloro-phen-yl)-3,3-di-methyl-thio-urea

Gamal A El-Hiti; Keith Smith; Amany S Hegazy; Mohammad Hayal Alotaibi; Benson M Kariuki

doi:10.1107/S1600536814011350

1-(2-Bromo-4-chloro-phen-yl)-3,3-di-methyl-thio-urea

Acta Crystallogr Sect E Struct Rep Online. 2014 May 24;70(Pt 6):o704. doi: 10.1107/S1600536814011350. eCollection 2014 Jun 1.

Authors

Gamal A El-Hiti¹, Keith Smith², Amany S Hegazy², Mohammad Hayal Alotaibi³, Benson M Kariuki²

Affiliations

¹ Cornea Research Chair, Department of Optometry, College of Applied Medical Sciences, King Saud University, PO Box 10219, Riyadh 11433, Saudi Arabia.
² School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, Wales.
³ Petrochemical Research Institute, King Abdulaziz City for Science and Technology, PO Box 6086, Riyadh 11442, Saudi Arabia.

Abstract

In the title compound, C9H10BrClN2S, the di-methyl-thio-urea group is twisted from the benzene ring plane by 54.38 (6)°. In the crystal, the amino groups are involved in the formation of N-H⋯S hydrogen bonds, which link the mol-ecules into chains along [010]. Weak C-H⋯Cl inter-actions further link these chains into layers parallel to the ab plane.