1-(4-Bromo-phen-yl)-3-(3-chloro-propan-oyl)thio-urea

Acta Crystallogr Sect E Struct Rep Online. 2014 May 21;70(Pt 6):o685. doi: 10.1107/S1600536814011209. eCollection 2014 Jun 1.

Abstract

The title compound, C10H10BrClN2OS, adopts a trans-cis conformation with respect to the position of the 3-chloro-propanoyl and 4-bromo-phenyl groups, respectively, against the thiono C=S bond across their C-N bonds. The benzene ring makes a dihedral angle of 9.55 (16)° with the N2CS thio-urea moiety. Intra-molecular N-H⋯O and C-H⋯S hydrogen bonds occur. In the crystal, mol-ecules are linked into chains along the c-axis direction by N-H⋯S, C-H⋯S and C-H⋯O hydrogen bonds.