1-(4-Chloro-butano-yl)-3-(3-chloro-phen-yl)thio-urea

Hamza M Abosadiya; Siti Aishah Hasbullah; Bohari M Yamin; Adibatul H Fadzil

doi:10.1107/S1600536814009295

1-(4-Chloro-butano-yl)-3-(3-chloro-phen-yl)thio-urea

Acta Crystallogr Sect E Struct Rep Online. 2014 May 17;70(Pt 6):o675. doi: 10.1107/S1600536814009295. eCollection 2014 Jun 1.

Authors

Hamza M Abosadiya¹, Siti Aishah Hasbullah¹, Bohari M Yamin², Adibatul H Fadzil³

Affiliations

¹ School of Chemical Sciences and Food Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor D.E., Malaysia.
² Low Carbon Research Group, School of Chemical Sciences and Food Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor D.E., Malaysia.
³ Faculty of Applied Sciences, Universiti Teknologi MARA (UiTM), 40450 Shah Alam, Selangor D.E., Malaysia.

Abstract

The two independent mol-ecules in the asymmetric unit of the title compound, C11H12Cl2N2OS, exhibit different conformations, with the benzene ring and the N2CS thio-urea group forming dihedral angles of 87.40 (18) and 69.42 (15)°. An intra-molecular N-H⋯O hydrogen bond is present in each mol-ecule. Two further N-H⋯O hydrogen bonds link the independent mol-ecules into a dimer. In the crystal, the dimers are linked by N-H⋯S and C-H⋯S hydrogen bonds, forming chains parallel to the c axis.