Coordination reaction between tetraphenylporphyrin and nickel on a TiO2(110) surface

Cici Wang; Qitang Fan; Shanwei Hu; Huanxin Ju; Xuefei Feng; Yong Han; Haibin Pan; Junfa Zhu; J Michael Gottfried

doi:10.1039/c4cc02919d

Coordination reaction between tetraphenylporphyrin and nickel on a TiO2(110) surface

Chem Commun (Camb). 2014 Aug 7;50(61):8291-4. doi: 10.1039/c4cc02919d.

Authors

Cici Wang¹, Qitang Fan, Shanwei Hu, Huanxin Ju, Xuefei Feng, Yong Han, Haibin Pan, Junfa Zhu, J Michael Gottfried

Affiliation

¹ National Synchrotron Radiation Laboratory and Collaborative Innovation Center of Suzhou Nano Science and Technology, University of Science and Technology of China, Hefei, 230029, P. R. China. jfzhu@ustc.edu.cn.

PMID: 24871136
DOI: 10.1039/c4cc02919d

Abstract

In situ metalation of tetraphenylporphyrin (2HTPP) (sub)monolayers with Ni on a TiO2(110) surface to nickel(II)-tetraphenylporphyrin (NiTPP) depends on temperature and order of deposition, and affects conformation and bonding geometry of the porphyrin.