1,10-Phenanthroline-5,6-dione ethanol monosolvate

Jing-Wei Dai; Zhao-Yang Li; Osamu Sato

doi:10.1107/S1600536814008241

1,10-Phenanthroline-5,6-dione ethanol monosolvate

Acta Crystallogr Sect E Struct Rep Online. 2014 Apr 18;70(Pt 5):o573. doi: 10.1107/S1600536814008241. eCollection 2014 May 1.

Authors

Jing-Wei Dai¹, Zhao-Yang Li², Osamu Sato¹

Affiliations

¹ Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan.
² Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, Japan.

Abstract

In the title compound, C12H6N2O2·C2H5OH, the mol-ecule of the 1,10-phenanthroline-5,6-dione is approximately planar, with a maximum deviation of 0.051 (1) Å. In the crystal, mol-ecules are linked by O-H⋯N and weak C-H⋯O hydrogen bonds, forming supra-molecular chains propagating along [110]. π-π stacking inter-actions are observed between the pyridine rings of neighbouring chains, the centroid-centroid separations being 3.6226 (11) and 3.7543 (11) Å.