Synthesis of fluorescent (benzyloxycarbonylamino)(aryl)methylphosphonates

Beilstein J Org Chem. 2014 Mar 28:10:741-5. doi: 10.3762/bjoc.10.68. eCollection 2014.

Abstract

The synthesis of a library of structurally variable aromatic esters of (benzyloxycarbonylamino)(aryl)methylphosphonic acids is described by means of the Oleksyszyn reaction. The library was enlarged by the application of a Suzuki-Miayra approach and by preparation of mixed esters.

Keywords: Oleksyszyn reaction; Z-aminophosphonate esters; aminophosphonates; organophosphorus.