Self-decoration of Pt metal particles on TiO(2) nanotubes used for highly efficient photocatalytic H(2) production

Chem Commun (Camb). 2014 Jun 11;50(46):6123-5. doi: 10.1039/c4cc01287a.

Abstract

Pt decorated TiO2 has, over the past decades, been a key material for photocatalytic hydrogen production. The present work shows that growing anodic self-organized TiO2 nanotubes from Ti-Pt alloy with a low Pt content of 0.2 at% leads to oxide nanotube layers that are self-decorated with Pt nanoparticles of 4-5 nm in diameter. The average particle spacing is in the range of ~50 nm and is partially adjustable by the anodization conditions. This intrinsic decoration of TiO2 nanotubes with Pt leads to a highly active photocatalyst for the production of H2 under UV or visible light conditions.