Impacts of human activities and sampling strategies on soil heavy metal distribution in a rapidly developing region of China

Abstract

The impacts of industrial and agricultural activities on soil Cd, Hg, Pb, and Cu in Zhangjiagang City, a rapidly developing region in China, were evaluated using two sampling strategies. The soil Cu, Cd, and Pb concentrations near industrial locations were greater than those measured away from industrial locations. The converse was true for Hg. The top enrichment factor (TEF) values, calculated as the ratio of metal concentrations between the topsoil and subsoil, were greater near industrial location than away from industrial locations and were further related to the industry type. Thus, the TEF is an effective index to distinguish sources of toxic elements not only between anthropogenic and geogenic but also among different industry types. Target soil sampling near industrial locations resulted in a greater estimation in high levels of soil heavy metals. This study revealed that the soil heavy metal contamination was primarily limited to local areas near industrial locations, despite rapid development over the last 20 years. The prevention and remediation of the soil heavy metal pollution should focus on these high-risk areas in the future.

Keywords: Heavy metal pollution; Human activities; Industrial; Sampling strategies; Soil.