Abstract
N-hydroxyphthalimide and N-hydroxysuccinimide have been arylated with diaryliodonium salts to provide N-aryloxyimides in excellent yields in short reaction times. A novel hydrolysis under mild and hydrazine-free conditions yielded aryloxyamines, which are valuable building blocks in the synthesis of oxime ethers and benzofurans.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzofurans / chemical synthesis
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Benzofurans / chemistry
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Catalysis
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Ethers / chemical synthesis
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Ethers / chemistry
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Molecular Structure
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Phthalimides / chemical synthesis*
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Phthalimides / chemistry
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Succinimides / chemical synthesis*
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Succinimides / chemistry
Substances
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Benzofurans
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Ethers
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Phthalimides
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Succinimides
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stemofuran A
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N-hydroxyphthalimide
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N-hydroxysuccinimide