This work describes the use of direct current (DC) cyclic voltammetry (CV) and alternating current (AC) electrochemical impedance spectroscopy (EIS) as a means to monitor an electrochemical interface of different mass flow direction induced polyaniline (PANI) film in IL (BmimPF6). Observed by SEM, vertical mass flow (VMF) and horizontal mass flow (HMF) induce porous nanorod and compact granular morphology of PANI, respectively. The present work explores in detail analysis of double layer capacitance, polarization resistance, diffusion mechanism, as well as other electrochemical features associated with the PANI-IL interface. A comparatively higher value of capacitance obtained for VMF PANI film from CV measurement confirms the higher electroactivity at the VMF electrode than the HMF film. Impedance spectroscopy, using a small amplitude perturbation, confirms the CV result. Impedance measurement gives a value of capacitance larger than that from CV where the amplitude of the perturbation is much larger. The implications of these results for its potential application in energy storage devices are discussed.