In the title compound, [Ti2(C16H14N2O2)2O2]·2CHCl3, the Ti(IV) atom in the centrosymmetric complex has a distorted octa-hedral N2O4 coordination environment and is linked via two μ2-oxido bridges into a dinuclear centrosymmetric com-plex, with a Ti⋯Ti separation of 2.7794 (8) Å. In the salen (N,N'-ethyl-enebis(salicyl-imine)) ligand, the two salicyl-imine units make a dihedral angle of 45.31 (5)°. The complex mol-ecules are stacked parallel to [100], forming channels in which the solvent chloro-form mol-ecules are located. C-H⋯O hydrogen-bonding inter-actions between the complex mol-ecules and the solvent mol-ecules consolidate the crystal packing.